var workbook = new XLWorkbook();
var ws = workbook.Worksheets.Add("Style Border");
var co = 2;
var ro = 1;
ws.Cell(++ro, co).Value = "BottomBorder = Thick; BottomBorderColor = Red";
ws.Cell(ro, co).Style.Border.BottomBorder = XLBorderStyleValues.Thick;
ws.Cell(ro, co).Style.Border.BottomBorderColor = XLColor.Red;
ws.Cell(++ro, co).Value = "LeftBorder = Thick; LeftBorderColor = Blue";
ws.Cell(ro, co).Style.Border.LeftBorder = XLBorderStyleValues.Thick;
ws.Cell(ro, co).Style.Border.LeftBorderColor = XLColor.Blue;
ws.Cell(++ro, co).Value = "TopBorder = Thick; TopBorderColor = Yellow";
ws.Cell(ro, co).Style.Border.TopBorder = XLBorderStyleValues.Thick;
ws.Cell(ro, co).Style.Border.TopBorderColor = XLColor.Yellow;
ws.Cell(++ro, co).Value = "RightBorder = Thick; RightBorderColor = Black";
ws.Cell(ro, co).Style.Border.RightBorder = XLBorderStyleValues.Thick;
ws.Cell(ro, co).Style.Border.RightBorderColor = XLColor.Black;
ws.Cell(++ro, co).Value = "DiagonalBorder = Thin; DiagonalBorderColor = Red; DiagonalUp = true";
ws.Cell(ro, co).Style.Border.DiagonalBorder = XLBorderStyleValues.Thin;
ws.Cell(ro, co).Style.Border.DiagonalBorderColor = XLColor.Red;
ws.Cell(ro, co).Style.Border.DiagonalUp = true;
ws.Cell(++ro, co).Value = "DiagonalBorder = Thin; DiagonalBorderColor = Red; DiagonalDown = true";
ws.Cell(ro, co).Style.Border.DiagonalBorder = XLBorderStyleValues.Thin;
ws.Cell(ro, co).Style.Border.DiagonalBorderColor = XLColor.Red;
ws.Cell(ro, co).Style.Border.DiagonalDown = true;
ws.Cell(++ro, co).Value = "DiagonalBorder = Thin; DiagonalBorderColor = Red; DiagonalUp = true; DiagonalDown = true";
ws.Cell(ro, co).Style.Border.DiagonalBorder = XLBorderStyleValues.Thin;
ws.Cell(ro, co).Style.Border.DiagonalBorderColor = XLColor.Red;
ws.Cell(ro, co).Style.Border.DiagonalUp = true;
ws.Cell(ro, co).Style.Border.DiagonalDown = true;
workbook.SaveAs("StylesBorder.xlsx");
You can also set the outside border of a cell/range in one shot, like this:
range.Style.Border.OutsideBorder = XLBorderStyleValues.Thick;