https://addons.mozilla.org/en-US/firefox/addon/firefox-new-container-tab/
Opening a new tab in a Firefox container is hell—you have to either hard press the new tab button or remember obscure, limited shortcuts. New Container Tab changes that: you use the shortcut (Windows) Ctrl+Shift+Comma or (macOS) Cmd+Shift+Comma, search for a container name, and press Enter. Furthermore, the container search box auto-suggests, so speed is guaranteed! You can also enable the option to 'auto-open' tabs once a match is found.
Note: You can always change default shortcuts at about:addons
> Settings (gear icon) > Manage Extension Shortcuts