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Update manual
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smaret committed May 16, 2015
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Expand Up @@ -142,6 +142,23 @@ computed by multiplying the densities of the reactants by :math:`k`.
Similarly the destruction rate of each reactant is computed by
multiplying the densities of the reactants by :math:`k`. Reactions in
Astrochem may have up to three reactants, and four products.

Ion - polar molecule reactions rates can be better described by one of
the two expressions (for more details, see the `KIDA database
documentation <http://bit.ly/1KBAHvq>`_):

.. math:: k = \alpha \beta \left( 0.62 + 0.4767 \gamma \left(
\frac{300}{T} \right)^{0.5} \right)
:label: ion-pol1

or:

.. math:: k = \alpha \beta \left( 1 + 0.0967 \gamma \left(
\frac{300}{T}^0.5 \right) + \frac{\gamma^2}{10.526}
\frac{300}{T} \right)^{0.5}
:label: ion-pol2

These two types of reactions are implemented in Astrochem.

Cosmic-ray ionization
~~~~~~~~~~~~~~~~~~~~~
Expand Down Expand Up @@ -1133,6 +1150,10 @@ example you may want to identify gas-phase reactions by numbers between
+---------------+---------------------------------------------------------------+
| 13 | Photo-ionization, Photo-dissociation |
+---------------+---------------------------------------------------------------+
| 14 | Ion - polar molecule reactions (type 1) |
+---------------+---------------------------------------------------------------+
| 15 | Ion - polar molecule reactions (type 2) |
+---------------+---------------------------------------------------------------+
| 20 | Freeze-out on grains |
+---------------+---------------------------------------------------------------+
| 21 | Thermal desorption |
Expand Down Expand Up @@ -1168,6 +1189,10 @@ internal time step.
+-------------+--------------------------+------------------+------------------------+----------------+
| 13 | :eq:`photo-ionization` | :math:`\alpha` | \- | \- |
+-------------+--------------------------+------------------+------------------------+----------------+
| 14 | :eq:`ion-pol1` | :math:`\alpha` | :math:`\beta` | :math:`\gamma` |
+-------------+--------------------------+------------------+------------------------+----------------+
| 15 | :eq:`ion-pol2` | :math:`\alpha` | :math:`\beta` | :math:`\gamma` |
+-------------+--------------------------+------------------+------------------------+----------------+
| 20 | :eq:`depletion` | :math:`S` | :math:`m/m_\mathrm{H}` | \- |
+-------------+--------------------------+------------------+------------------------+----------------+
| 21 | :eq:`thermal-desorption` | \- | :math:`m/m_\mathrm{H}` | :math:`E_{b}` |
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